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Chef Spike Mendelsohn may have competed on Bravo's culinary reality show Top Chef -- twice -- but he still didn't expect to be recruited for Food Network's Next Iron Chef: Super Chefs, which premieres Sunday at 9/8c. "I got the phone call out of nowhere. I was actually quite surprised," Mendelsohn tells TVGuide.com. "I didn't expect them to cast me as part of this crew, alongside the other ones. I was definitely honored to have the opportunity. There are a lot of chefs involved that I look up to and I follow their careers. To be standing next to them, was kind of like, 'OK, you made it.'"