McConaughey has been tapped to host the Nov. 21 episode, with Adele as the musical guest, NBC announced Monday.
It will be McConaughey's first time hosting SNL since 2003. Adele previously appeared on the show behind her debut album, 19, in 2008, before she had broken big in the United States. The singer will be promoting her highly-anticipated upcoming album, 25, which will have been released the day before SNL airs. Listen to first single "Hello" here.