Tricia Helfer Tricia Helfer

Not only is Molly Parker (Tricia Helfer) great at figuring out why women kill, she's great at catching the killers too!

Must-see new shows of 2014

In this exclusive sneak peek of the Killer Women series premiere, it truly is 'til death do us part at this Texan wedding gone wrong, when a mysterious murderer shoots the bride right at the altar. But Molly wastes no time going after the assassin in a high-speed car chase that isn't to be missed.

Killer Women premieres Tuesday at 10/9c on ABC.