Jesse James Jesse James

Jesse James plans to give his first TV interview since his breakup with Sandra Bullock on Nightline, ABC announced Wednesday.

Michelle "Bombshell" McGee: I had an affair with Jesse James out of "boredom"

James will discuss his past, his time in rehab and why he cheated on Bullock in an interview with Vicki Mabrey, slated to air Tuesday, May 25 at 11:35/10:35c.

Shortly after Bullock won the best-actress Academy Award for her performance in The Blind Side, Michelle "Bombshell" McGee came forward claiming she had an affair with James. In April, Bullock filed for divorce.

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The Monster Garage star recently returned home from a treatment facility to deal with "personal issues," according to People.