Gwyneth Paltrow Gwyneth Paltrow

Oscar award-winning actress Gwyneth Paltrow will make her live musical debut on the 44th annual Country Music Awards, airing Wednesday, Nov. 10 (8/7c on ABC).

Paltrow will take the stage with famed country rock singer Vince Gill at the CMAs to perform the title track from her upcoming film Country Song.

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Country Song, also starring Tim McGraw, follows the story of a rising young star who gets romantically involved with Paltrow's character while they tour the country with her husband and a beauty-queen-turned-singer (Gossip Girl's Leighton Meester).

Hosted by Carrie Underwood and Brad Paisley, the CMAs will also feature performances by Dierks Bentley, Kenny Chesney, Lady Antebellum, Miranda Lambert, Paisley, Rascal Flatts, Reba, Blake Shelton, George Strait, Sugarland, Underwood, Keith Urban and Taylor Swift.