Erica Durance Erica Durance

Erica Durance will guest-star on Charlie's Angels, TVLine reports.

Durance joins the freshman series as Samantha Masters, a "tough-as-nails, Glock-toting CIA operative" who was once romantically entangled with Bosley (Ramon Rodriguez).

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The role reunites Durance with her former Smallville boss Miles Millar, who is an executive producer on the new Angels.

Charlie's Angels, which stars Minka Kelly, Rachael Taylor and Annie Ilonzeh as the angels, premieres Thursday, Sept. 21, at 8/7c.