Nina Dobrev, Blake Lively Nina Dobrev, Blake Lively

The CW has announced its fall premiere dates, including those for the highly anticipated new show Arrow, the CW's top-rated drama Vampire Diaries and the final season of Gossip Girl.

Arrow, which was the most-added new drama on's Watchlist, will kick off on Wednesday, Oct. 10 at 8/9c. Season 3 of The Vampire Diaries premieres the following night at 8/7c. And fans can venture back to the Upper East Side for Gossip Girl's sixth and final season beginning on its new night, Monday, Oct. 8 at 9/8c.

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See all the premiere dates below.

Tuesday, Oct. 2
8/7c: Hart of Dixie

Wednesday, Oct. 3
9/8c: Supernatural

Monday, Oct. 8
8/7c: 90210
9/8c: Gossip Girl

Wednesday, Oct. 10
8/7c: Arrow *

Thursday, Oct. 11
8/7c: The Vampire Diaries
9/8c: Beauty and the Beast *

Tuesday, Oct. 16
9/8c: Emily Owens, M.D.*

Friday, Oct. 19
9/8c: Nikita

* denotes new series