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13 Episodes 1965 - 1966
Episode 1
Sun, Sep 12, 196530 mins
Ed and Wilbur channel James Bond in this surrealistic episode. While riding, the duo notice a spy ring dropping information, beginning with a lovely lady rider on a brown mare. Coming back another day, they try to distract the lady, so Ed can get information on the ring from the lady's horse. Wilbur is captured after a "sword fight" with a branch versus a goon's litter stick. Tied up in a shack, Wilbur manages to pull Ed's tail with a rope, signaling a light that's picked up by a nearby Coast Guard vessel via Morse Code. The Coast Guard rescues Wilbur just before they are about to kill him and captures the spy ring with their microfilm of a new USAF plane. There is a B-plot about Wilbur's father-in-law visiting, but that's just so much fluff. The man doesn't think much about Wilbur. This could easily have been a "dream episode", as it's quite outlandish, even for "Mr. Ed".
Episode 2
Sun, Sep 19, 196530 mins
The neighbor's teenage son is playing loud rock 'n' roll records late at night, and it's preventing a good night's sleep for Wilbur and Carol.
Episode 3
Sun, Sep 26, 196530 mins
Having previously been successful in helping to apprehend Russian spies possessing stolen microfilm, Wilbur and Ed are now after them for trying to sell an American military secret.

Episode 4
Sun, Oct 3, 196530 mins
The Russian spies have stolen an unknown American secret formula, so SIA (Secret Intelligence Agency) enlists Wilbur to find out which one. Mister Ed joins him, and Carol is left wondering where Wilbur is at all hours of the night.
Episode 5
Sun, Oct 10, 196530 mins
Mister Ed writes a hot and spicy autobiography.
Episode 6
Sun, Oct 17, 196530 mins
The SIA (Secret Intelligence Agency) once again enlists Wilbur to figure out how secret papers are being stolen out of filing cabinets, which are right under the agent's noses. In order to help solve the case, Mister Ed needs to speak with a monkey, so he uses a zebra as a translator.
Episode 7
Sun, Oct 24, 196530 mins
Mister Ed wins a late model color TV, and he demands that Wilbur put it in the barn.
Episode 8
Sun, Oct 31, 196530 mins
Much to Ed's dismay, Carol and Wilbur agree to cat-sit for a friend who is vacationing in Hawaii for an entire week.
Episode 9
Sun, Nov 7, 196530 mins
Ed wants Wilbur to get rid of a bearskin rug that was given to Carol and him by her father.
Episode 10
Sun, Dec 26, 196530 mins
Ed wants Wilbur to help him get married to another horse, and Carol's father thinks that Wilbur is in need of mental help.
Episode 11
Sun, Jan 2, 196630 mins
Ed refuses to continue to wear a saddle and he demands that Wilbur ride him bareback from now on, so Wilbur gets a motorcycle to retaliate.
Episode 12
Sun, Jan 9, 196630 mins
When Ed discovers that he is of Cherokee descent, he refuses to participate in the Pioneer Parade. Unfortunately for Wilbur, he has already promised Carol's Dad that Ed would do it as a favor for him.
Episode 13
Sun, Feb 6, 196630 mins
Mister Ed goes to school so he can become a veterinarian.