20 of 20Brad Pitt and Jennifer Aniston
Hollywood's picture-perfect golden couple singlehandedly fueled tabloid sales when they split in January 2005 after five years of marriage and seven years together. Pitt quickly hooked up with his Mr. and Mrs. Smith co-star Angelina Jolie, sparking rumors that he had cheated on the Friends star. Brangelina are now engaged with six children, and Aniston got engaged to her Wanderlust co-star Justin Theroux in August 2012.
Photo By: Evan Agostini/Getty Images