Usually hidden behind glasses and braces on Ugly Betty, America Ferrera shines with confidence off set.

She's a firebrand as Brothers & Sisters' Kitty, but Calista Flockhart radiates a calm, warm glow on the red carpet.

Football may be part of her day job, but there's nothing rough around the edges when Friday Night Lights' Connie Britton steps off the field.

Trading in her island garb for evening wear, Lost's Elizabeth Mitchell is illuminating like no Other.

She's a stubborn fighter as Lost's Kate, but Evangeline Lilly's exotic beauty makes a bold statement on the red carpet.

Academy award-winning actress Gwyneth Paltrow stands out on screen and off with her simple, untouched glow.

Always lighting up the red carpet with her friendly personality, Alias alumna Jennifer Garner has an inviting glow that is sure to turn heads.

She may have played the no-frills tomboy Mary on 7th Heaven, but Jessica Biel's striking beauty is undeniable on the red carpet.

She dons her scrubs well as emotionally charged Izzie on Grey's Anatomy, but Katherine Heigl has that old Hollywood glamour that begs for attention.

Lucy Liu - whose Cashmere Mafia hits the tube midseason - may be tough, but her soft, natural glow is friendly to the camera.