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The hottest stars hit the hottest events

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1 of 14 Jean Baptiste Lacroix/WireImage.com

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HitMiley Cyrus looks radiant and appropriately grown-up at the premiere of the much-anticipated Hannah Montana: The Movie in Hollywood. We love that she matched her sassy fringe dress with a fun leather jacket and boots.
2 of 14 Jean Baptiste Lacroix/WireImage.com

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MissMitchel Musso, who is starring in Hannah Montana: The Movie is too emo for the red carpet at the movie's premiere. And, while we can't deny that Dancing with the Stars' Shawn Johnson is as cute as a button, we're not feeling the beat of this busy spring frock.
3 of 14 Jean Baptiste Lacroix

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HitHannah Montana: The Movie's Taylor Swift looks classy and lovely in this fun cocktail dress, but after seeing Miley's outfit, doesn't she seem a bit overdressed?
4 of 14 Steve Granitz/WireImage.com

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HitVanessa Williams brightens up the entire red carpet at the Hannah Montana premiere in this fun shift dress, paired with a chunky turquoise necklace.
5 of 14 Theo Wargo/WireImage.com

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DrawKate Moss and Jennifer Lopez make a mismatched pair at the Topshop/Topman launch dinner at Balthazar in New York City. They're both sporting fashion-forward attire, but Kate's dress is too delicate for her rocker look, while JLo's gladiators negate the simplicity of her look.
6 of 14 Jamie McCarthy/WireImage.com

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HitJill Hennessy looks like a complete knockout in this red cocktail dress at the premiere of Lymelife during the Gen Art Film Festival. We love when stars work it on the carpet!
7 of 14 Steve Granitz/WireImage.com

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Hit (faux tan notwithstanding)Anne Hathaway proves once again that she has fantastic taste in this gorgeous, sequined gown. She strikes a pose with Valentino at the premiere of Valentino: The Last Emperor. And while the guest of honor donned a gorgeous suit, it's hard for us to overlook his oompa-loompa-like tanning disaster.
8 of 14 Jeff Vespa/WireImage.com

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MissGwyneth Paltrow continues her trend of making fugly fashion choices that wash her out. You'd think she'd try a little harder considering that she's at the premiere of Valentino: The Last Emperor, a documentary about the legendary designer.
9 of 14 Steve Granitz/WireImage.com

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DrawThis is probably a cuter look in person, but Rose McGowan isn't doing her ensemble any favors with a slouchy pose and apathetic expression at the Valentino premiere.
10 of 14 Jeffrey Ufberg/WireImage.com

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MissMarg Helgenberger visits The Late Show with David Letterman to promote CSI's 200th episode. With all that crime-fighting under her belt, she should know that this outfit would get her arrested by the fashion police. The silky halter dress doesn't show off her smokin' bod, and the white sandals clash with the dress' busy pattern.
11 of 14 Michael Bezjian/WireImage.com

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HitActor Billy Zane arrives at the 2009 Beverly Hills Film Festival's opening night in a stunning eggplant suit. We're not sure about the sunglasses, but we definitely dig his super-sexy mojo.
12 of 14 Jemal Countess/WireImage.com

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MissGossip Girl's Taylor Momsen, posing here at the Topshop/Topman launch dinner, has done us proud by finally lightening up her raccoon-eye makeup. She disappoints, though, with her overwrought '80s love — not to mention her cranky expression.
13 of 14 Dimitrios Kambouris/WireImage.com

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MissYikes, Amber Tamblyn! What are you doing wearing your 8th grade art teacher's outfit for back-to-school night at Nylon's 10th anniversary party? Next time, how about a cute little cocktail dress and heels.
14 of 14 James Devaney/WireImage.com

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HitOnly Gossip Girl's Ed Westwick, seen here on location as Chuck Bass, could get away with raspberry pants! Ed, we bow down to your awesome preppiness.