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The Best TV Couples of All Time

Photo Gallery: The Best TV Couples of All Time
Giovanni Rufino/The CW 
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Giovanni Rufino/The CW 
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Chuck and Blair (Ed Westwick and Leighton Meester), Gossip Girl

No two people deserve each other more than the scheming and vindictive Chuck and Blair. Together, you don’t want them on your bad side, but somehow when these two are a couple, they bring out the best in each other.