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Sydney and Vaughn (Jennifer Garner and Michael Vartan), Alias
Dating is hard enough. But the bright side for us common folk is that we don't have to worry about espionage groups keeping us apart, not to mention trying to kill us, like Sydney and Vaughn did. Let's not even mention the lost two years, fake identity, kidnapping and wife/saboteur. At least they end up happily ever after with their daughter-in-spy-training.