Jimmy Kimmel hosts the 35th annual event. Slated to perform: Mary J. Blige, Chris Brown, Daughtry, Celine Dion, Duran Duran, Fergie, the Jonas Brothers, Alicia Keys, Lenny Kravitz, Queen Latifah, Avril Lavigne, Maroon 5, Rascal Flatts, Rihanna, Nicole Scherzinger, Sugarland and will.i.am. Justin Timberlake, Beyoncé, Linkin Park and Daughtry lead the field with three nominations each.