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As the A-list couple calls it quits, was there evidence of trouble in their awkward kisses?

Shaun Harrison
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1 of 16 Fotonoticias/WireImage.com

As the a-list couple calls it quits, was there evidence of trouble in their awkward kisses?

2 of 16 Kevin Mazur/WireImage.com

2005 backstage at the MTV Movie Awards.

3 of 16 Evan Agostini/Getty Images

2005 at the War Of The Worlds premiere in New York City.

4 of 16 MJ Kim/Getty Images

2005 at the UK premiere of War of the Worlds.

5 of 16 Steve Granitz/WireImage.com

2005 at the UK premiere of War of the Worlds.

6 of 16 Tony Barson/WireImage.com

2005 in Marseille, France.

7 of 16 Tony Barson/WireImage.com

2005 in Marseille, France.

8 of 16 Francois Durand/Getty Images

2005 leaving a Paris railway station.

9 of 16 Kevin Winter/Getty Images

2005 at the premiere of Batman Begins in Hollywood.

10 of 16 Getty Images

2005 at the David di Donatello Italian film awards ceremony in Rome, Italy.

11 of 16 Chris Polk/FilmMagic.com

2006 during the Mission: Impossible III fan screening in Los Angeles.

12 of 16 Timothy A. Clary/AFP/Getty Images

2007 after Katie finished running the New York City Marathon.

13 of 16 Dimitrios Kambouris/WireImage.com

2007 at the 3rd Annual Museum of the Moving Image Black Tie Salute in New York City.

14 of 16 Gregg DeGuire/WireImage.com

2007 at the Mentor LA's Promise Gala.

15 of 16 Eric Charbonneau/WireImage.com

2007 at the Vanity Fair Oscar Party.

16 of 16 Charley Gallay/Getty Images

2008 at the Mad Money premiere in Los Angeles.