Gwyneth Paltrow, Country Strong
Paltrow is no stranger to singing. She showcases her not-so-bad vocal chops in 2000's karaoke/deadbeat dad drama Duets, alongside Huey Lewis. (She even married a rock star, Coldplay frontman Chris Martin.) Next up, she will show off her chops on Glee and in Country Strong, the Oscar winner plays a faded country star trying to resurrect her career. Paltrow sounds the part in the music video for the movie's title track, which she performed live on the CMAs.