Breaking Bad's Anna Gunn is sexy and chic in a black gown with a deep V-neck and a wide open back.

Kelly Osbourne is sparkling in a black Jenny Packham cap-sleeved gown with a sheer beaded overlay.

Cougar Town's Busy Phillips is showing off her growing baby bump in a form-fitting, long-sleeved black gown and a statement necklace.

Les Miserables' breakout star Eddie Redmayne stands out in a brown velvet suit.

30 Rock actress Katrina Bowden looks gorgeous in a silvery Badgley Mischka dress.

Modern Family's Ariel Winter looks like a Disney princess with a tulle ball gown and sheer sleeves with flower appliques.

Nancy O'Dell looks like a mermaid in her aqua dress with sequin cutouts.

Ty Burrell adds a touch of pizzazz to his Brooks Brothers suit with a striped tie.

Scandal star Kerry Washington rocks it in a sparkling, bright-white two-piece gown.

Sofia Vergara is a little too flashy in an ill-fitting one-strap gown.

Downton Abbey star Michelle Dockery keeps it simple in a high-neck black gown with sheer side panels.

We would've loved Jane Krakowski in this mandarin-colored Kaufman Franco dress, but the fit was a little off.

Mad Men's Elisabeth Moss looks stunning in a tea-length dress with a sweetheart neck and sparkly skirt, not to mention Forever Mark earrings worth a whopping million dollars.

Glee's mean girl Naya Rivera showed off her figure in a tight black Donna Karen Atelier gown with a deep V-neck.

Jessica Chastain looks stunning in a red-hot strapless mermaid gown with a tiny train.

Naomi Watts is flawless in an intricately beaded Marchesa gown.

Nurse Jackie's Jaimie Alexander is a show-stopper in her black gown.

Bright pink is beautiful on Freida Pinto, but her hair is a little too matronly and the dress is a little bulky on top.

Helen Hunt is channeling her inner rock star in a Ramona Caveza beaded gown with a matching choker and bangles.

Zuleikha Robinson looks nothing like a Homeland villain in a tie-dyed strapless Memeka by Gustavo Cadile gown with a fitted top and ball-gown skirt.

Amanda Seyfried is stunning in a Zac Posen trumpet-style gown and a long Lorraine Schwartz necklace.

Jennifer Lawrence is beautiful in a chic blue Dior Couture strapless frock with simple jewels and a side ponytail.

Recent Golden Globes host Tina Fey is stunning in a black Oscar de la Renta gown with a sweetheart neckline and a shiny belt that accentuates her tiny waist.

Julie Bowen's pulled-back ponytail puts the focus on her cap-sleeved, leather gown.

January Jones' dress is nice, but it's hard to get past that Ziggy Stardust-inspired 'do.

Jennifer Garner rarely misses the mark, and again she's a hit in this beaded strapless gold stunner.

Could Aubrey Anderson-Emmons from Modern Family look anymore adorable in her ruffled dress, tights and Mary Janes?

Homeland star and new mom Claire Danes is a little more messy than her usual chic look and the lipstick is way too My So-Called Life.

Mad Men actress Kiernan Shipka is adorable and age-appropriate in a tea-length, pale-pink printed dress.

The Vampire Diaries' leading lady Nina Dobrev chose a bold pink short-sleeved gown with a touch of silver accented by her dangling earrings.

If you ignore Alec Baldwin's messy hair, he and wife Hilaria Thomas are a pretty well-dressed couple.

Angela Kinsey is all wrong in a lace top with spaghetti straps and way too many fabrics.

Has Amy Poehler always been this sexy? She's looking hot in a tight black dress and smoky eyes.

While the sleeve length is a bit awkward, this blue lace gown is a big step up for Mayim Bialik, who usually dresses more frumpy.

Julianna Margulies always chooses a unique gown, but the skirt is just too billowy for her figure.

Big Bang Theory's Kelly Cuoco is barely recognizable in blunt bangs and a too-short red dress.

Lea Michele is stunning in a strapless pink gown and straight ombre hair.

Anne Hathaway's goth look comprises of short black hair, red lipstick and in a black tulle dress that's sheer over the legs.

It probably wouldn't matter what Bradley Cooper was wearing, but nonetheless his suit and bowtie is timeless.

Justin Timberlake is disappointing in a houndstooth suit that clashes with a striped shirt.

Gabby Douglas shows off her Olympic gold-winning legs in a blue cocktail dress.

Idol winner-turned-actress Jordin Sparks shows off her slimmed-down figure in a blue halter gown that hugs her in all the right places.

Idina Menzel had the right idea with the cut, but unfortunately it's a little too tight in certain area and the train should've stuck with one color.

Ellie Kemper looks a little washed-out in a seafoam-green Reem Acra dress with a side train.

Julianne Moore's dress isn't flattering and at any moment we fear she could have a nip slip.

The blue color of Kate Flannery's dress is a little overpowering with her pale skin, but there's no denying that the dress complements her svelte figure and signature red locks.

There's not much to be said about the frock Rose Byrne is wearing other than it looks like a patterned, belted piece of fabric.

The Office's Jenna Fischer looks glam in a short-sleeved, loose-fitting gown that's cinched at the waist and has just the right amount of sparkle.

Alfre Woodard is stunning in a lime-colored gown that ruches on top and drapes on the bottom.