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Sydney Bristow (Jennifer Garner), Alias
Few modern-day femme spies are more kickass than Sydney, who went through hell — losing her fiancé and BFF, learning her mom is a KGB spy and getting brainwashed for two years — and back in her SD-6 double agent life. Through it all, Syd kept her cool and took down every baddie with one vintage roundhouse kick after another. Besides, has anyone ever looked better in wigs and spandex?