4 of 18
Chloe Bennet, Marvel's Agents of S.H.I.E.L.D.
After briefly appearing as Gunnar's lady-love Hailey on Nashville, Bennet moves into sci-fi territory on S.H.I.E.L.D.. Her character, Skye, is a free-spirited computer hacker who uses her savvy to gain the upper hand once she's recruited as an agent. Because she's a civilian, her background is mostly a mystery to the other members of S.H.I.E.L.D., but, like most viewers of the show will be, she's known to be obsessed with superheroes. Thanks to Bennet's wit and charm, Skye could become an unlikely fan favorite on the show.