Chris Harrison

Chris Harrison is set to interview Oscar nominee Natalie Portman and show host James Franco, but his real worry is Ryan Seacrest's hair.

Paulina, Daisy Fuentes join TV Guide Network

"We have competing hair stylists and I'm trying to poof mine up," Harrison jokes. "See what I've got going? This is like a Seacrest-plus-four."

TVGuide.com asked the TV Guide Network host about his biggest faux pas, who he'd hijack an interview for, and who he wants to win at Sunday's Academy Awards.

Check out our Academy Awards section

TV Guide Network's red carpet coverage begins Sunday at 5 ET/2 PT with Academy Awards Red Carpet Countdown, followed by Academy Awards Red Carpet with Chris Harrison at 6 ET/3 PT. The 83rd Annual Academy Awards start at 8:30/7:30c on ABC.

And be sure to tune in to TV Guide Network's
Academy Awards Red Carpet Fashion Wrap the next night at 8/7c.