Isaiah Mustafa and Annie Ilonzeh

Old Spice hunk Isaiah Mustafa has joined the cast of ABC's Charlie's Angels, TVGuide.com has confirmed.

Mustafa, who recently appeared in a handful of Chuck episodes, will play Ray Goodson, an athletic and chiseled Miami PD detective who was previously engaged to Kate (Annie Ilonzeh), but broke it off after she was busted for being a dirty cop.

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Their paths will cross starting in Episode 4, when the Angels — Minka Kelly and Rachael Taylor included — take on a case he's also working on.

TVLine.com first reported the news.

Charlie's Angels premieres Thursday, Sept. 22, at 8/7c.